SP1 Silicon feedstock
CRYSTALCLEAR is dedicated to crystalline
silicon photovoltaic (PV) modules. Modules form the heart of any PV
system and crystalline silicon technology has a global
market share of over 90%, illustrating the importance of
the CRYSTALCLEAR working area. The solar cells in
such modules are made of very high purity silicon, the so-called
feedstock. Silicon is, after oxygen, the most
abundant element in the crust of the earth. It is produced in large
quantities by reaction of quartz (silicon oxide) and cokes
(basically carbon) at high temperature in electric arc
furnaces.
For solar cells (as well as for microelectronic chips) a
high grade of silicon is required. Only then can
the electrical properties be controlled sufficiently to allow use
in devices. It is custom to speak about "solar grade" and
"electronic grade" material. The production of this
high-purity silicon requires advanced equipment,
is expensive and energy-intensive. Until now, the PV industry has
used surplus and "off-spec" electronic grade silicon from the
microelectronics industry. This is however an inherently
limited source, which can no longer fulfill the
needs of the rapidly growing (recently by 30-40%
per year) PV industry. Assuring security of silicon supply has
therefore become one of this industry's main challenges.
Worldwide, several alternative manufacturing methods for
high-purity silicon are under development. These
methods aim at combining sufficient quality for use in
high-efficiency solar cells with reduced cost compared to today's
mainstream electronic grade silicon production. One of the main
aims of Subproject 1 in
CRYSTALCLEAR is to test silicon
from pilot production of these alternative methods on its
suitability for use in advanced solar cell production. After
initial screening on some basic properties the material is tested
"in real life" by several industrial and institute partners, and
feedback is provided to the manufacturer.
The other major aim of SP1 is to gain better scientific
understanding and practical know-how on solar grade
silicon. In SP1 available materials are studied in detail, but also
model materials are produced and investigated, with emphasis on the
impact of chemical impurities in the silicon on solar cell
performance. This will result in well-founded
specifications for major impurities in solar grade silicon
and will allow design of optimum processes for silicon production
as well as dedicated cell manufacturing processes.